TA Instruments

50% SIH 50% PCHINA-0027f

29/04/2022 3:22:20 p. m.

Sample name	50% SIH 50% PCHINA
Sample notes	 
Experiment notes	
Operator	
Sample density	1,000 g/cm^3
Results file name	50% SIH 50% PCHINA
Run number	27 
Results directory	C:\Ta\Data\Ar1500\Ar1500\DIEGO ROA
Experiment was run on	29/04/2022 3:22:20 p. m.

Procedure name	Flow procedure
Procedure notes	

Step name	Conditioning Step 1
Step notes	
Perform step	Yes
Initial temperature	25,0 C
Wait for correct temperature	Yes
Do set temperature	Yes
Perform pre-shear	No
Perform equilibration	Yes
Equilibration duration	0:02:00 hh:mm:ss
Wait for zero velocity	No
Purge gas only	No

Step name	Stepped flow step 1
Step notes	
Perform step	Yes
Ramp type	Stepped flow
Start controlled variable	shear rate 1,000E-3 1/s
End controlled variable	shear rate 0,01000 1/s
Ramp mode	log 
Points per decade	3 
Temperature	25,0 C
Wait for temperature	No
Constant time	0:00:10 hh:mm:ss
Average last x seconds	0:00:05 hh:mm:ss
Motor mode	auto 
Integer rotation averaging	No

Step name	Stepped flow step 2
Step notes	
Perform step	Yes
Ramp type	Stepped flow
Start controlled variable	shear rate 0,01000 1/s
End controlled variable	shear rate 0,1000 1/s
Ramp mode	log 
Points per decade	3 
Temperature	25,0 C
Wait for temperature	No
Constant time	0:00:10 hh:mm:ss
Average last x seconds	0:00:05 hh:mm:ss
Motor mode	auto 
Integer rotation averaging	No

Step name	Stepped flow step 3
Step notes	
Perform step	Yes
Ramp type	Stepped flow
Start controlled variable	shear rate 0,1000 1/s
End controlled variable	shear rate 1,000 1/s
Ramp mode	log 
Points per decade	5 
Temperature	25,0 C
Wait for temperature	No
Constant time	0:00:10 hh:mm:ss
Average last x seconds	0:00:05 hh:mm:ss
Motor mode	auto 
Integer rotation averaging	No

Step name	Stepped flow step 4
Step notes	
Perform step	Yes
Ramp type	Stepped flow
Start controlled variable	shear rate 1,000 1/s
End controlled variable	shear rate 100,0 1/s
Ramp mode	log 
Points per decade	8 
Temperature	25,0 C
Wait for temperature	No
Constant time	0:00:10 hh:mm:ss
Average last x seconds	0:00:05 hh:mm:ss
Motor mode	auto 
Integer rotation averaging	No

Step name	Conditioning Step 2
Step notes	
Perform step	Yes
Initial temperature	25,0 C
Wait for correct temperature	Yes
Do set temperature	Yes
Perform pre-shear	Yes
Pre-shear variable	10,00 1/s
Pre-shear duration	0:00:10 hh:mm:ss
Motor mode	auto 
Perform equilibration	Yes
Equilibration duration	0:02:00 hh:mm:ss
Wait for zero velocity	No
Purge gas only	No

Step name	Temperature ramp step 1
Step notes	
Perform step	Yes
Ramp type	Temperature ramp
Start temperature	25,0 C
End temperature	90,0 C
Wait for start temperature	Yes
Ramp rate	10,00 C/min
Delay time	0:00:09 hh:mm:ss
Controlled variable	shear rate 10,00 1/s
Motor mode	auto 

Step name	Temperature ramp step 2
Step notes	
Perform step	Yes
Ramp type	Temperature ramp
Start temperature	90,0 C
End temperature	90,0 C
Wait for start temperature	No
Ramp duration	0:05:00 hh:mm:ss
Delay time	0:00:09 hh:mm:ss
Controlled variable	shear rate 10,00 1/s
Motor mode	auto 

Step name	Temperature ramp step 3
Step notes	
Perform step	Yes
Ramp type	Temperature ramp
Start temperature	90,0 C
End temperature	25,0 C
Wait for start temperature	No
Ramp rate	10,00 C/min
Delay time	0:00:09 hh:mm:ss
Controlled variable	shear rate 10,00 1/s
Motor mode	auto 

Step name	Conditioning Step 3
Step notes	
Perform step	Yes
Initial temperature	25,0 C
Wait for correct temperature	Yes
Do set temperature	Yes
Perform pre-shear	Yes
Pre-shear variable	1,000 1/s
Pre-shear duration	0:00:10 hh:mm:ss
Motor mode	auto 
Perform equilibration	Yes
Equilibration duration	0:02:00 hh:mm:ss
Wait for zero velocity	No
Purge gas only	No

Step name	Stepped flow step 5
Step notes	
Perform step	Yes
Ramp type	Stepped flow
Start controlled variable	shear rate 1,000E-3 1/s
End controlled variable	shear rate 0,01000 1/s
Ramp mode	log 
Points per decade	3 
Temperature	25,0 C
Wait for temperature	No
Constant time	0:00:10 hh:mm:ss
Average last x seconds	0:00:05 hh:mm:ss
Motor mode	auto 
Integer rotation averaging	No

Step name	Stepped flow step 6
Step notes	
Perform step	Yes
Ramp type	Stepped flow
Start controlled variable	shear rate 0,01000 1/s
End controlled variable	shear rate 0,1000 1/s
Ramp mode	log 
Points per decade	3 
Temperature	25,0 C
Wait for temperature	No
Constant time	0:00:10 hh:mm:ss
Average last x seconds	0:00:05 hh:mm:ss
Motor mode	auto 
Integer rotation averaging	No

Step name	Stepped flow step 7
Step notes	
Perform step	Yes
Ramp type	Stepped flow
Start controlled variable	shear rate 0,1000 1/s
End controlled variable	shear rate 1,000 1/s
Ramp mode	log 
Points per decade	5 
Temperature	25,0 C
Wait for temperature	No
Constant time	0:00:10 hh:mm:ss
Average last x seconds	0:00:05 hh:mm:ss
Motor mode	auto 
Integer rotation averaging	No

Step name	Stepped flow step 8
Step notes	
Perform step	Yes
Ramp type	Stepped flow
Start controlled variable	shear rate 1,000 1/s
End controlled variable	shear rate 100,0 1/s
Ramp mode	log 
Points per decade	8 
Temperature	25,0 C
Wait for temperature	No
Constant time	0:00:10 hh:mm:ss
Average last x seconds	0:00:05 hh:mm:ss
Motor mode	auto 
Integer rotation averaging	No

Step name	Post-Experiment Step
Step notes	
Perform step	Yes
Do set temperature	No
Set temperature system idle	No

Geometry name	Starch cell
Geometry notes	Starch cell
Geometry material	High temperature
gap	5500 micro m
Calibration factor	10800 
Gap offset	0 micro m
Geometry inertia	2,224 micro N.m.s^2
Shear rate factor	1,000 
Shear stress factor	10800 1/m^3
Measurement system factor	10800 1/m^3
Fluid density factor	1,000E-15 m^5
Normal force factor	1,000 1/m^2
Backoff distance	1,25E5 micro m

Gap zero mode	Standard
Sample compression	none 
Compression distance	1000,0 micro m
Compression velocity	100,0 micro m/s
Fine velocity	1000,0 micro m/s
Coarse velocity	3000,0 micro m/s
Other velocity	3000,0 micro m/s
Current temperature system	Starch cell
Temperature control	Enabled 
Purge gas only	No
Temperature calibration	Peltier plate - 0 micro m/C
	Water bath - 0 micro m/C
	Torsion oven - plate - 0 micro m/C
	Torsion oven - solid sample - 0 micro m/C
	Peltier concentric cylinders - 0 micro m/C
	None - 0 micro m/C
	Stress relaxation - 0 micro m/C
	Current temperature system - 0 micro m/C
Cooling water temperature	5,0 C
Cooling water range	15,0 C
Bearing friction correction	Yes
Bearing friction	1,222 micro N.m/(rad/s)
Bearing offset	0 micro N.m
Temperature system span and offset	Peltier plate - span 1,0000 , offset 0 C
	Water bath - span 1,0000 , offset 0 C
	Torsion oven - plate - span 1,0000 , offset 0 C
	Torsion oven - solid sample - span 1,0000 , offset 0 C
	Peltier concentric cylinders - span 1,0000 , offset 0 C
	None - span 1,0000 , offset 0 C
	Stress relaxation - span 1,0000 , offset 0 C
	Current temperature system - span 1,0000 , offset 0 C
Bearing mapping type	fast 
Number of mapping iterations	1
Instrument type (MType)	AR1500ex
Firmware version	  8.29  27/10/09
Configuration version (CnfVer)	301
Parameter version (PrmVer)	301
PCB Number	*NOT_SET*
IP address	172.23.191.2
Software version	V5.8.2
Windows version	Windows XP 6.2
Instrument inertia	15,97 micro N.m.s^2
Auto increment run number	Yes
Prompt for file name at start of run	Yes
Auto save results file	Yes
Results file storage	Consecutive steps of same type to 1 file 
Temperature tolerance	0,2 C
Temperature duration	0:00:10 hh:mm:ss
Wait for temperature even if OK	Yes
Gap tolerance	4 micro m
Gap duration	0:00:02 hh:mm:ss
Override wait for gap	No
Velocity tolerance	0,1000 rad/s
Zero speed after pre-shear	Leave as is 
Zero normal force before run	No
Zero timer before run	Before pre-shear 
Non-equilibrium minimum velocity	3,000E-4 rad/s
Zero strain at the start of each flow step	Yes
Inertia correction	No
Collect negative shear rate data if stress is positive	Yes
Collect all points	No
Display flow point graph during run	Yes
Store flow point graph with results	Yes
Store images to the results for flow steps	No
Creep zero displacement	Yes
Store images to the results for creep steps	No
Standard creep image store frequency	10 s
Repeated creep image store frequency in repeats	10 
Display oscillation waveform graph during run	Yes
Store oscillation waveform graph with results	Yes
Display strain control tries during run	Yes
Store strain control tries with results	Yes
Store images to the results for oscillation steps	No
Stress relaxation zero displacement	Yes
Store images to the results for stress relaxation steps	No
Flow torque limit	10,00 micro N.m
Flow velocity limit	1,000E-3 rad/s
Oscillation torque limit	5,00 micro N.m
Oscillation displacement limit	1,00E-5 rad
Oscillation raw phase limit	170,0 degrees
Oscillation minimum normal force limit	0 N
Oscillation maximum normal force limit	0 N
Flow velocity tolerance	5,00 %
Oscillation torque tolerance	1,00 %
Oscillation displacement tolerance	5,00 %
Oscillation velocity tolerance	5,00 %
Temperature tolerance	1,0 C

Stepped flow step 1

shear stress	shear rate	viscosity	time	temperature	normal stress
Pa	1/s	Pa.s	s	C	Pa

0,01099	1,000E-3	10,99	9,9530	25,0	0
0,01892	2,151E-3	8,793	19,890	25,0	0
0,03147	4,640E-3	6,783	29,984	25,0	0
0,04440	9,999E-3	4,441	40,000	25,0	0

Stepped flow step 2

shear stress	shear rate	viscosity	time	temperature	normal stress
Pa	1/s	Pa.s	s	C	Pa

0,05626	0,01000	5,626	9,9840	25,0	0
0,07656	0,02152	3,558	20,047	25,0	0
0,08718	0,04640	1,879	30,109	25,0	0
0,1111	0,1000	1,111	40,156	25,0	0
0,09401	0,1000	0,9400	50,250	25,0	0

Stepped flow step 3

shear stress	shear rate	viscosity	time	temperature	normal stress
Pa	1/s	Pa.s	s	C	Pa

0,08705	0,1000	0,8704	9,9680	25,0	0
0,06445	0,1585	0,4067	20,031	25,0	0
0,06103	0,2511	0,2430	30,062	25,0	0
0,07188	0,3981	0,1805	40,156	25,0	0
0,1281	0,6312	0,2029	50,250	25,0	0
0,06252	1,000	0,06252	60,312	25,0	0

Stepped flow step 4

shear stress	shear rate	viscosity	time	temperature	normal stress
Pa	1/s	Pa.s	s	C	Pa

0,06033	0,9999	0,06033	9,9690	25,0	0
0,07516	1,334	0,05636	20,063	25,0	0
0,06002	1,778	0,03375	30,204	25,0	0
0,06656	2,371	0,02807	40,329	25,0	0
0,05955	3,162	0,01883	50,422	25,0	0
0,05379	4,217	0,01275	60,500	25,0	0
0,06999	5,623	0,01245	70,532	25,0	0
0,1052	7,499	0,01403	80,625	25,0	0
0,1574	10,00	0,01574	90,704	25,0	0
0,3151	13,34	0,02363	100,80	25,0	0
0,4636	17,78	0,02607	110,84	25,0	0
0,6987	23,71	0,02946	120,94	25,0	0
1,085	31,62	0,03431	131,03	25,0	0
1,601	42,17	0,03798	141,09	25,0	0
2,617	56,23	0,04654	151,20	25,0	0
4,201	74,99	0,05602	161,25	25,0	0
6,287	100,0	0,06287	171,33	25,0	0

Temperature ramp step 1

shear stress	shear rate	viscosity	time	temperature	normal stress
Pa	1/s	Pa.s	s	C	Pa

0,2010	9,998	0,02010	9,0040	25,0	0
0,1844	10,00	0,01844	18,008	25,5	0
0,1827	10,00	0,01827	27,012	26,6	0
0,1770	10,00	0,01770	36,012	28,1	0
0,1739	10,00	0,01739	45,004	29,8	0
0,1705	10,00	0,01705	54,012	31,5	0
0,1693	10,00	0,01693	63,012	33,2	0
0,1641	10,00	0,01641	72,020	34,9	0
0,1635	10,00	0,01635	81,008	36,5	0
0,1597	10,00	0,01597	90,020	38,2	0
0,1550	10,00	0,01550	99,008	39,7	0
0,1530	10,00	0,01530	108,01	41,3	0
0,1523	10,00	0,01523	117,02	42,8	0
0,1501	10,00	0,01501	126,01	44,3	0
0,1473	10,00	0,01473	135,01	45,9	0
0,1462	10,00	0,01462	144,00	47,3	0
0,1428	10,00	0,01428	153,00	48,8	0
0,1461	10,00	0,01461	162,02	50,3	0
0,1401	10,00	0,01401	171,01	51,8	0
0,1363	10,00	0,01363	180,02	53,3	0
0,1351	10,00	0,01351	189,02	54,8	0
0,1345	9,999	0,01345	198,00	56,3	0
0,1307	10,00	0,01307	207,01	57,8	0
0,1382	10,00	0,01382	216,02	59,3	0
0,1347	10,00	0,01347	225,01	60,8	0
0,1293	10,00	0,01293	234,01	62,3	0
0,1302	10,00	0,01302	243,02	63,8	0
0,1301	10,00	0,01301	252,01	65,3	0
0,1343	10,00	0,01343	261,01	66,7	0
0,1345	10,00	0,01345	270,02	68,3	0
0,1392	10,00	0,01392	279,02	69,9	0
0,1466	10,00	0,01466	288,01	71,3	0
0,1643	10,00	0,01643	297,03	72,8	0
0,1990	10,00	0,01990	306,02	74,3	0
0,3181	10,00	0,03181	315,01	75,9	0
0,6491	9,999	0,06491	324,02	77,6	0
1,445	10,00	0,1445	333,01	79,3	0
2,750	10,00	0,2750	342,01	80,6	0
4,286	10,00	0,4286	351,01	81,9	0
5,502	10,00	0,5503	360,00	83,3	0
6,663	10,00	0,6663	369,01	84,8	0

Temperature ramp step 2

shear stress	shear rate	viscosity	time	temperature	normal stress
Pa	1/s	Pa.s	s	C	Pa

7,642	10,00	0,7642	9,0040	86,7	0
7,997	10,00	0,7997	18,004	89,0	0
8,574	10,00	0,8574	26,996	90,1	0
9,112	9,998	0,9114	36,000	90,6	0
11,63	9,999	1,163	45,008	91,0	0
10,94	10,00	1,094	53,988	91,1	0
9,290	10,00	0,9291	62,992	91,1	0
9,024	10,00	0,9024	71,996	91,0	0
8,932	10,00	0,8932	80,996	90,8	0
8,807	10,00	0,8807	90,008	90,6	0
8,670	10,00	0,8670	99,008	90,5	0
8,607	10,00	0,8606	108,00	90,4	0
8,499	9,999	0,8500	117,00	90,3	0
8,404	10,00	0,8404	126,00	90,2	0
8,258	10,00	0,8258	134,99	90,1	0
8,099	9,999	0,8099	144,01	90,1	0
7,998	10,00	0,7997	153,00	90,1	0
7,997	10,00	0,7997	162,00	90,0	0
7,845	10,00	0,7845	171,01	90,0	0
7,753	10,00	0,7752	180,00	90,0	0
7,642	9,999	0,7642	189,00	90,0	0
7,526	10,00	0,7526	198,00	90,0	0
7,496	10,00	0,7496	207,00	90,0	0
7,407	10,00	0,7406	215,99	90,0	0
7,380	10,00	0,7379	225,00	90,0	0
7,252	10,00	0,7251	234,00	90,0	0
7,216	9,999	0,7217	243,00	90,0	0
7,139	10,00	0,7138	251,99	90,0	0
7,046	10,00	0,7046	261,01	90,0	0
7,020	10,00	0,7019	270,00	90,0	0
6,950	10,00	0,6950	279,02	90,0	0

Temperature ramp step 3

shear stress	shear rate	viscosity	time	temperature	normal stress
Pa	1/s	Pa.s	s	C	Pa

6,859	10,00	0,6859	9,0000	90,0	0
6,737	10,00	0,6737	17,992	89,4	0
6,555	10,00	0,6554	26,996	86,1	0
6,405	10,00	0,6405	35,996	85,4	0
6,340	10,00	0,6340	44,984	84,8	0
6,305	10,00	0,6305	53,988	83,0	0
6,244	10,00	0,6244	62,996	81,3	0
6,227	10,00	0,6227	71,996	80,4	0
6,269	10,00	0,6269	80,996	78,3	0
6,278	10,00	0,6278	89,996	76,8	0
6,287	10,00	0,6287	98,988	75,9	0
6,403	10,00	0,6402	107,99	73,6	0
6,408	10,00	0,6407	117,00	72,5	0
6,509	9,999	0,6510	126,00	71,0	0
6,563	10,00	0,6562	135,00	68,9	0
6,638	9,999	0,6639	144,01	68,2	0
6,742	10,00	0,6742	152,99	66,1	0
6,797	10,00	0,6797	162,01	64,7	0
6,914	10,00	0,6913	171,00	63,6	0
7,014	10,00	0,7013	179,98	61,5	0
7,104	9,999	0,7104	188,99	60,6	0
7,312	9,999	0,7313	198,00	58,7	0
7,447	10,00	0,7447	207,00	57,1	0
7,629	10,00	0,7628	215,99	56,0	0
7,869	10,00	0,7868	225,00	54,1	0
8,040	10,00	0,8041	233,99	52,8	0
8,280	10,00	0,8280	243,00	51,3	0
8,572	9,999	0,8573	251,98	49,6	0
8,874	9,999	0,8875	260,99	48,3	0
9,085	10,00	0,9085	270,00	46,7	0
9,409	10,00	0,9409	279,00	45,2	0
9,631	10,00	0,9630	287,99	43,8	0
9,985	9,999	0,9986	296,99	42,2	0
10,09	10,00	1,009	305,99	40,8	0
10,44	10,00	1,044	315,00	39,3	0
10,71	10,00	1,071	323,99	37,8	0
10,98	10,00	1,098	333,00	36,3	0
11,30	9,999	1,130	341,98	34,8	0
11,63	10,00	1,163	350,99	33,3	0
11,98	10,00	1,197	359,99	31,9	0
12,48	9,999	1,249	369,01	30,4	0

Stepped flow step 5

shear stress	shear rate	viscosity	time	temperature	normal stress
Pa	1/s	Pa.s	s	C	Pa

0,1236	9,974E-4	124,0	9,9840	25,0	0
0,3160	2,154E-3	146,8	20,109	24,9	0
0,5860	4,641E-3	126,3	30,187	25,0	0
1,004	9,998E-3	100,4	40,265	25,0	0

Stepped flow step 6

shear stress	shear rate	viscosity	time	temperature	normal stress
Pa	1/s	Pa.s	s	C	Pa

1,222	9,999E-3	122,2	9,9370	24,9	0
1,662	0,02154	77,14	20,015	25,0	0
2,190	0,04641	47,18	30,062	25,0	0
2,811	0,1000	28,11	40,125	25,0	0
2,821	0,1000	28,21	50,156	24,9	0

Stepped flow step 7

shear stress	shear rate	viscosity	time	temperature	normal stress
Pa	1/s	Pa.s	s	C	Pa

2,881	0,1000	28,81	9,9380	25,0	0
3,347	0,1585	21,12	20,016	25,0	0
3,948	0,2512	15,72	30,063	25,0	0
4,702	0,3981	11,81	40,172	24,9	0
5,650	0,6310	8,954	50,141	25,0	0
6,716	1,000	6,716	60,250	25,0	0

Stepped flow step 8

shear stress	shear rate	viscosity	time	temperature	normal stress
Pa	1/s	Pa.s	s	C	Pa

6,497	1,000	6,497	9,9060	25,0	0
7,276	1,334	5,456	19,906	24,9	0
8,175	1,778	4,597	30,047	25,0	0
9,240	2,371	3,896	40,188	25,0	0
10,53	3,162	3,331	50,250	25,0	0
12,04	4,217	2,855	60,344	25,0	0
13,90	5,623	2,472	70,391	25,0	0
15,98	7,499	2,131	80,469	25,0	0
18,46	10,00	1,846	90,578	25,0	0
21,02	13,34	1,576	100,67	25,0	0
23,90	17,78	1,344	110,75	25,0	0
26,77	23,71	1,129	120,83	25,0	0
29,66	31,62	0,9378	130,89	25,0	0
32,56	42,17	0,7722	141,02	25,0	0
37,49	56,23	0,6667	151,11	25,0	0
44,76	74,99	0,5969	161,17	25,1	0
48,22	100,0	0,4822	171,22	25,0	0

